Biosystems Engineering

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Browsing Biosystems Engineering by Author "John, M. J."

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    Effect of alkaline pretreatment on the thermal behavior and chemical properties of rice husk varieties in relation to activated carbon production
    (Springer, 2019-07-19) . Menya, E; Olupot, P. W.; Storz, H.; Lubwama, M.; Kiros, Y.; John, M. J.
    Thermal behavior and chemical properties of selected raw and NaOH-pretreated rice husk varieties were investigated. NaOH- pre treatment process involved soaking 5 g rice husk samples in 40 mL of 2%w/v NaOH, shaking (400 rpm) and heating (50 C) for 3 h. NaOH- pretreated samples were water-washed, oven-dried, and milled for use in the determination of their thermal behavior and surface functional groups. Alkaline wash water was also analyzed for sugar components. Thermal decomposition temperatures, degradation rates, and the subsequent mass losses varied from one rice husk variety to another. These thermal properties increased after NaOH pretreatment of the rice husk varieties, reducing their char yields (17.1–20.4% db). These changes mainly had to do with the lignin, hemicellulose, and ash removal from the rice husk varieties, as confirmed by their FTIR analysis, as well as by the sugar composition analysis of their alkaline wash-water. Consequently, the FTIR spectra differed between the raw and NaOH-pretreated rice husk varieties
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    Optimization of pyrolysis conditions for char production from rice husks and its characterization as a precursor for production of activated carbon
    (Springer, 2019-03-13) Menya, E.; Olupot, P. W.; Storz, H.; Lubwama, M.; Kiros, Y.; John, M. J.
    Response surface methodology was employed to optimize pyrolysis conditions for the production of char with maximum yield, fixed carbon content, and minimum ash content from Uganda’s New Rice for Africa (NERICA) 1 rice husk variety. The aim was to obtain rice husk char with more suitable properties as an activated carbon precursor. Mathematical models were developed to explain the relationships between the experimental responses and the pyrolysis parameters of temperature (400–600 °C), heating rate (10–25 °C min−1), and heating period (60–120 min). The optimized rice husk char was further characterized for elemental and proximate compositions, thermal behaviour, specific surface area, as well as surface functional groups. Results from the analysis of variance (ANOVA) revealed that the quadratic model best fits each of the responses. Pyrolysis temperature had the greatest influence on each of the responses, followed by heating period, and lastly heating rate. Optimum pyrolysis conditions were found to be temperature (406 °C), heating rate (10 °C min−1), and heating period (60 min), resulting in char yield, fixed carbon, and ash contents of 35.26, 55.39, and 35.01% dry basis, respectively. Compared to raw rice husk, the resulting rice husk char was found more suited as activated carbon precursor, due to its enriched carbon content (60.35%) and specific surface area (123.9 m2g−1). Thermogravimetric analysis of the rice husk char revealed that thermal activation temperatures were higher than 400 °C may be required to considerably devolatilize the char, forming a more porous activated carbon.