Stannate (IV) and Antimonate (V) Hexahydroxy-anion complexes with Di- and Polyhydric Phenols

Abstract

An identification has been achieved of only 1:1 and 1:2 chelates of hexahydroxystannate (IV) anions with ortho (i.e., 1,2)-diphenols, using potentiometric and conductimetric techniques. Lack of evidence for organo-richer complexes in aqueous media is in contrast to antimonite (V) hexahydroxy anions and tellurate (VI), which are each able to form a tris (catecholate).

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Keywords

Stannate (IV, Antimonate (V), Tellurate (VI, Diphenols, Complex-formation

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